Download the LG Adhesives MSDS Sheet (Adobe Reader required)
DATE: 2004-1-10
1. IDENTIFICATION OF THE SUBSTANCE/ PREPARATION AND THE COMPANY/UNDERTAKING
Identification of the preparation: Hi-Macs JOINT ADHESIVE KIT – COMPONENT A
Supplier:
LG CHEM. LTD (Chung Ju Plant)
150, SONG JEONG DONG, HEUNG DEOK GU,
CHUNG JU CITY, CHUNG BUK, KOREA
TEL: 82-043-261-7399
FAX : 82-043-261-7169
|
Emergency telephone number:
Tel: 82-02-3773-3817
|
2. COMPOSITION/ INFORMATION ON INGREDIENTS:
| Chemical nature of the preparation: Synthetic resin(s) and filler(s). |
| Hazardous components: |
|
| methyl methacrylate: |
30-60 weight(%) |
| XI: R36/37/38-43 |
|
| CAS-No: |
80-62-6 |
| EC-No: |
201-297-1 |
3. HAZARDS IDENTIFICATION
| Most important hazards |
Highly flammable.
Irricating to eyes, respiratory system and skin.
May cause sensitization by skin contact
|
| Specific hazards |
None known |
4. FIRST AID MEASURES
| Inhalation: |
Move to fresh air. Oxigen or artificial respiration if needed. Consult physician
after significant exposure. |
| Eye contact: |
Rinse thoroughly with plenty of water at least 18 minutes and consult a
Physician. Keep eye wide open while rinsing. |
| Skin contact: |
Wash off immediately with soap and plenty of water. |
| Ingestion: |
Never give anything by mouth to unconscious person. Rinse mouth .
Ingest activated charcoal. Call a physician immediately. |
5. FIRE-FIGHTING MEASURES:
Suitable extinguishing media: Use dry chemical, CO2, Water spray or “alcohol” foam.
Extinguishing media which must not be used for safety reasons: high volume water jet
6. ACCIDENTAL RELEASE MEASURES
| Personal precautions: |
Ensure adequate ventilation. Use personal protective equipment.
Remove all sources of ignition. |
| Environmental precautions: |
Do not let product enter drains. |
| Methods for cleaning up: |
Soak up with inert absorbent material. Clean with detergents.
Avoid solvents. |
7. HANDILING AND STORAGE
| Handling: |
Technical measures/Precautions: Provide sufficient air exchange and/or exhaust
in work rooms. Keep product and empty container away from heat and sources
of ignition. Take precautionary measures against static discharges. |
| Storage: |
Technical measures/Storage conditions: Keep container tightly closed. Keep in a
well-ventilated place.
Incompatible products not applicable
Packing material not applicable |
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal
protective
equipment
Respiratory protection: |
Repeated and prolonged exposure to solvents may cause brain and
Nervous system damage. It is good practice in industrial hygiene to
Avoid contact with solvents by using appropriate protective measures whenever possible. |
| Eye protection: |
safety glasses |
| Hand protection: |
solvent-resistant gloves |
| Hygiene measures: |
Keep away from food, drink and animal feeding stuffs. Wash hands before
Breaks and at the end of workday. |
| Exposure controls |
National occupational exposure limits
methyl methacrylate: TLV-TWA=100 ml/m3=410 mg/m3/A4/ACGIH(1997) |
9. PHYSICAL AND CHEMICAL PROPERTIES
| Appearance: |
|
|
| |
Form: |
liquid |
| |
Color: |
various |
| |
Odour: |
acrylic |
| PH: |
(°C (at g/l H2O) |
not applicable |
| Flash point: |
10°C closed up |
|
| Vapour pressure: |
( 20°C) 39hps |
|
| Autoignition temperature: |
430°C |
|
| Relative density:(°C) |
from 1.20kg/l
To 1.24kg/l |
|
| Solubility: |
|
|
| |
Water Solubility(°C) |
partly miscible g/l |
| Viscosity:(°C) |
no data available mpa.s |
|
| Explosion limits: |
-lower 2.1 vol. %
-upper 12.5 vol. % |
|
10. STABILITY AND REACTIVITY:
| Conditions to avoid: |
No decomposition if stored and applied as directed. |
| Hazardous decomposition products: |
methyl methacrylate monomer |
| Further information: |
vapours are heavier than air and may spread along floors.
vapours may from explosive mixtures with air. |
11. TOXICOLOGICAL INFORMATION
Repeated and prolonged exposure to solvents may cause brain and nervous system damage.
Acute toxicity: methyl methacrylate: LD50/oral/rac = 7872 mg/kg, RTECS, 47796
Local effects not applicable
12. ECOLOGICAL INFORMATION
Ecotoxicity effects no data available
13. DISPOSAL CONSIDERATIONS
| Waste from residues / unused products: |
Do not allow material to contaminate ground
water system. |
| Contaminated packaging: |
Can be incinerated . when in compliance with local regulations. |
14. TRANSPORT INFORMATION
| ADR/RID |
|
|
|
| |
Class: 3 |
Item: 5( C ) |
ADR/RID=Labels: 3 |
| |
TREM-CARD: 30G80 |
HI/UN NO: 1133 |
|
| |
Proper shipping name: Adhesives |
| |
|
|
|
| ICAO |
|
|
|
| |
UN/ID NO : 1133 |
Class: 3 |
Sub risks: |
| |
Packing group: III |
ICAO-Labels: Flammable liquid |
| |
Proper shipping name: Adhesives |
| |
|
|
|
| IMO |
|
|
|
| |
Class: 3.2 |
IMDG Page: 3174 |
Sub risks: |
| |
Packing group: III |
IMO-Labels: Flammable liquid |
| |
Pms: 3 –05 |
MPAG: 330 |
|
| |
Proper shipping name: Adhesives |
15. REGULARTORY INFORMATION
The product is classified and labeled in accordance with EC-Directive 88/379
| Symbol(s): |
Xi -irritant, F -Rightly flammable |
| Contents: |
methyl methacrylate |
| R-phrase: |
R11- Rightly flammable
R/36/37/38-Irritating to eyes, respiratory system and skin
R43-May cause sensitization by skin contact
S16-Keep away from source of ignition – No smoking
S23-Do not breathe vapour
S24/25-Avoid contact with skin and eyes
S37-Wear suitable gloves
S51-Use only in well ventilated areas |
16. OTHER INFORMATION
When used in a mixture, read the labels and safety data sheet of all components,
END USE: adhesives.
Do not use in medical applications involving permanent implantation in the human body.
The information provided in this safety data sheet is correct to the best of our knowledge,
Information and belief at the date of its publication. The information given is designed only
As a guidance for safe handling, use, processing, storage, transportation, disposal and release
And is not to be considered a warranty or quality specification. The information relates only to
The specific material designated and may not be valid for such material used in combination
With any other materials or in any process, unless specified in the text.
1. IDENTIFICATION OF THE SUBSTANCE/ PREPARATION AND THE COMPANY/UNDERTAKING
Identification of the preparation: Hi-Macs JOINT ADHESIVE KIT – COMPONENT B
Supplier:
LG CHEM. LTD (Chung Ju Plant)
150, SONG JEONG DONG, HEUNG DEOK GU,
CHUNG JU CITY, CHUNG BUK, KOREA
TEL: 82-043-261-7399
FAX : 82-043-261-7169 |
Emergency telephone number
Tel: 82-02-3773-3817 |
2. COMPOSITION/ INFORMATION ON INGREDIENTS:
Chemical nature of the preparation: benzoyl peroxide, plasticiser
Hazardous components:
| Benzoyl peroxide:≥3.0 weight(%) *Tube Type: 5.0 weight(%), Cartridge Type: 3.1 weight(%) |
| XI: 36-43 |
|
| CAS-No: |
94-36-0 |
| EC-No: |
202-327-6 |
| Butyl benzoyl phthalate:≥60weight(%) *Tube Type: 95.0weight(%), Cartridge Type: 60weight(%) |
| CAS-No: |
84-74-2 |
| EC-No: |
201-557-4 |
3. HAZARDS IDENTIFICATION
| Most important hazards: |
May cause sensitization by skin contact |
| Specific hazards: |
None known |
4. FIRST AID MEASURES
| Inhalation: |
Move to fresh air. Oxigen or artificial respiration if needed. Consult physician
after significant exposure. |
| Eye contact: |
Rinse thoroughly with plenty of water at least 18 minutes and consult a
Physician. Keep eye wide open while rinsing. |
| Skin contact: |
Wash off immediately with soap and plenty of water. |
| Ingestion: |
Never give anything by mouth to unconscious person. Rinse mouth .
Ingest activated charcoal. Call a physician immediately. |
5. FIRE-FIGHTING MEASURES:
Suitable extinguishing media: Use dry chemical, CO2, Water spray or “alcohol” foam.
Extinguishing media which must not be used for safety reasons: high volume water jet
6. ACCIDENTAL RELEASE MEASURES
| Personal precautions: |
Ensure adequate ventilation. Use personal protective equipment.
Remove all sources of ignition. |
| Environmental precautions: |
Do not let product enter drains. |
| Methods for cleaning up: |
Soak up with inert absorbent material. Clean with detergents.
Avoid solvents. |
7. HANDILING AND STORAGE
| Handling: |
Technical measures/Precautions: Keep product and empty container away from heat
and sources of ignition. Safe handling advice: do not smoke. |
| Storage: |
Technical measures/Storage conditions: Keep at temperatures below 30℃. Water mist
may be used to cool closed containers.
Incompatible products: Reacts violently in contact with acids, amines, driers.
Polimerization accelerators and easily oxidized materials.
Packing material : not applicable |
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
| Personal protective equipment |
| Respiratory protection: |
Repeated and prolonged exposure to solvents may cause brain and
Nervous system damage. It is good practice in industrial hygiene to
Avoid contact with solvents by using appropriate protective measures
Whenever possible. |
| Eye protection: |
safety glasses |
| Hand protection: |
solvent-resistant gloves |
| Hygiene measures: |
Keep away from food, drink and animal feeding stuffs. Wash hands before
Breaks and at the end of workday. |
| Exposure controls: |
National occupational exposure limits
Benzoyl peroxide: TLV-TWA=5 mg/m3/A4/ACGIH(1997)
Butyl benzoyl phthalate: TLV-TWA=5 mg/m3/A4/ACGIH(1997) |
9. PHYSICAL AND CHEMICAL PROPERTIES
| Appearance: |
|
|
| |
Form: |
liquid |
| |
Color: |
light yellow |
| Odour: |
slight |
|
| PH: (°C) (at g/l H2O): |
not applicable |
|
| Decomposition temperature: |
103°C |
|
| Flash point: |
above 100°C |
|
| Autoignition temperature: |
no data available °C |
|
| Vapour pressure:( 147°C) |
1.3hps |
|
| Relative density: (°C) |
from 1.03kg/l to 1.07kg/l |
|
| Solubility: |
|
|
| |
Water Solubility(°C) |
Immiscible g/l |
| Viscosity:(°C) |
no data available mpa.s |
|
| Explosion limits: |
-lower no data available vol. %
-upper no data available vol. % |
|
10. STABILITY AND REACTIVITY:
Conditions to avoid : Decomposition starting from 103℃: Benzoyl peroxide 100%
Materials to avoid: Reacts violently in contact with acids, amines, driers, polymerization
Accelerators and easily oxidized materials.
Hazardous decomposition products: benzoic acid, biphenyls, benzeno
11. TOXICOLOGICAL INFORMATION
Repeated and prolonged exposure to solvents may cause brain and nervous system damage.
Acute toxicity: Benzoyl Peroxide : LD50/oral/rac = 7710 mg/kg, RTECS, 19455
Butyl benzoyl phthalate : LD50/oral/rac = 8000 mg/kg, RTECS, 59814
Local effects not applicable
12. ECOLOGICAL INFORMATION
Ecotoxicity effects no data available
13. DISPOSAL CONSIDERATIONS
| Waste from residues / unused products: |
Do not allow material to contaminate ground
water system. Prevent product from entering drains. |
| Contaminated packaging: |
Can be incinerated . when in compliance with local regulations. |
14. TRANSPORT INFORMATION UN-NO: 1133
| ADR/RID |
|
|
|
| |
Class: 3 |
Item: 5( C ) |
ADR/RID=Labels: 3 |
| |
TREM-CARD: 30G80 |
HI/UN NO: 1133 |
|
| |
Proper shipping name: Adhesives |
| |
|
|
|
| ICAO |
|
|
|
| |
UN/ID NO : 1133 |
Class: 3 |
Sub risks: |
| |
Packing group: III |
ICAO-Labels: Flammable liquid |
| |
Proper shipping name: Adhesives |
| |
|
|
|
| IMO |
|
|
|
| |
Class: 3.2 |
IMDG Page: 3174 |
Sub risks: |
| |
Packing group: III |
IMO-Labels: Flammable liquid |
| |
Pms: 3 –05 |
MPAG: 330 |
|
| |
Proper shipping name: Adhesives |
15. REGULARTORY INFORMATION
| The product is classified and labeled in accordance with EC-Directive 88/379 |
| Symbol(s): |
Xi -irritant |
| Contents: |
Benzoyl peroxide |
| R-phrase: |
R43-May cause sensitization by skin contact
S14-Keep away from easily oxidisable materials
S16-Keep away from source of ignition – No smoking
S24/25-Avoid contact with skin and eyes
S37-Wear suitable gloves |
16. OTHER INFORMATION
When used in a mixture, read the labels and safety data sheet of all components,
END USE: adhesives.
Do not use in medical applications involving permanent implantation in the human body.
The information provided in this safety data sheet is correct to the best of our knowledge,
Information and belief at the date of its publication. The information given is designed only
As a guidance for safe handling, use, processing, storage, transportation, disposal and release
And is not to be considered a warranty or quality specification. The information relates only to
The specific material designated and may not be valid for such material used in combination
With any other materials or in any process, unless specified in the text.
Download Entire MSDS PDF
LG ADHESIVE COMPETITIVE TEST RESULTS*
| |
MAJOR COMPETITORS |
|
| CLASSIFICATION |
UNIT |
LG |
D |
S |
I |
REMARK |
| Flexural Strength |
24°C, KGF/mm2 |
4.26 |
3.62 |
3.9 |
2.9 |
|
| Gel Time |
20°C, Min |
13 |
15 |
15 |
14 |
|
| Cure Time |
20°C, Min |
25 |
45 |
30 |
35 |
|
| Color Change |
H16(AL/WHITE) |
5 |
5 |
4 |
3 |
5= No Color Change
|
|
1= Significant Color Change |
* Testing conducted using a 250ml tube in a controlled LG testing lab environment
Download Competitive Test Results PDF
